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Abstract We study 15 thermonuclear X-ray bursts from 4U 1820–30 observed with the Neutron Star Interior Composition Explorer (NICER). We find evidence of a narrow emission line at 1.0 keV and three absorption lines at 1.7, 3.0, and 3.75 keV, primarily around the photospheric radius expansion phase of most bursts. The 1.0 keV emission line remains constant, while the absorption features, attributed to wind-ejected species, are stable but show slight energy shifts, likely due to combined effects of Doppler and gravitational redshifts. We also examine with NICER the “aftermath” of a long X-ray burst (a candidate superburst observed by MAXI) on 2021 August 23 and 24. The aftermath emission recovers within half a day from a flux depression. During this recovery phase, we detect two emission lines at 0.7 and 1 keV, along with three absorption lines whose energies decrease to 1.57, 2.64, and 3.64 keV. Given the nature of the helium white dwarf companion, these absorption lines during the aftermath may originate from an accretion flow, but only if the accretion environment is significantly contaminated by nuclear ashes from the superburst. This provides evidence of temporary metal enhancement in the accreted material due to strong wind loss. Moreover, we suggest that the absorption features observed during the short X-ray bursts and in the superburst aftermath share a common origin in heavy nuclear ashes enriched with elements like Si, Ar, Ca, or Ti, either from the burst wind or from an accretion flow contaminated by the burst wind. 

Abstract Suzuki−Miyaura cross‐coupling reactions are used to modify the tyrosine residues onBombyx morisilkworm silk proteins using a water‐soluble palladium catalyst. First, model reactions using tyrosine derivatives are screened to determine optimal reaction conditions. For these reactions, a variety of aryl boronic acids, solvents, buffers, and temperature ranges are explored. Qualitative information on the reaction progress is collected via high‐performance liquid chromatography (HPLC), mass spectrometry (MS), and nuclear magnetic resonance (NMR). Optimized reactions are then applied to silk proteins. It is demonstrated the ability to modify silk fibroin in solution by first iodinating the tyrosine residues on the protein, and then carrying out Suzuki‐Miyaura reactions with a variety of boronic acid derivatives. Modification of silk is confirmed with NMR, ion‐exchange chromatography (IEC), UV‐vis, and infrared spectroscopy (IR). 

Abstract With an increasing number of continental‐scale hydrologic models, the ability to evaluate performance is key to understanding uncertainty and making improvements to the model(s). We hypothesize that any model, running a single set of physics, cannot be “properly” calibrated for the range of hydroclimatic diversity as seen in the contenintal United States. Here, we evaluate the NOAA National Water Model (NWM) version 2.0 historical streamflow record in over 4,200 natural and controlled basins using the Nash‐Sutcliffe Efficiency metric decomposed into relative performance, and conditional, and unconditional bias. Each of these is evaluated in the contexts of meteorologic, landscape, and anthropogenic characteristics to better understand where the model does poorly, what potentially causes the poor performance, and what similarities systemically poor performing areas share. The primary objective is to pinpoint traits in places with good/bad performance and low/high bias. NWM relative performance is higher when there is high precipitation, snow coverage (depth and fraction), and barren area. Low relative skill is associated with high potential evapotranspiration, aridity, moisture‐and‐energy phase correlation, and forest, shrubland, grassland, and imperviousness area. We see less bias in locations with high precipitation, moisture‐and‐energy phase correlation, barren, and grassland areas and more bias in areas with high aridity, snow coverage/fraction, and urbanization. The insights gained can help identify key hydrological factors underpinning NWM predictive skill; enforce the need for regionalized parameterization and modeling; and help inform heterogenous modeling systems, like the NOAA Next Generation Water Resource Modeling Framework, to enhance ongoing development and evaluation. 

Despite extensive research and technology to reduce the atmospheric emission of Pb from burning coal for power generation, minimal attention has been paid to Pb associated with coal ash disposal in the environment. This study investigates the isotopic signatures and output rates of Pb in fly ash disposal in China, India, and the United States. Pairwise comparison between feed coal and fly ash samples collected from coal-fired power plants from each country shows that the Pb isotope composition of fly ash largely resembles that of feed coal, and its isotopic distinction allows for tracing the release of Pb from coal fly ash into the environment. Between 2000 and 2020, approx. 236, 56, and 46 Gg Pb from fly ash have been disposed in China, India, and the U.S., respectively, posing a significant environmental burden. A Bayesian Pb isotope mixing model shows that during the past 40 to 70 years, coal fly ash has contributed significantly higher Pb (∼26%) than leaded gasoline (∼7%) to Pb accumulation in the sediments of five freshwater lakes in North Carolina, U.S.A. This implies that the release of disposed coal fly ash Pb at local and regional scales can outweigh that of other anthropogenic Pb sources. 

Abstract We present the tidal disruption event (TDE) AT2022lri, hosted in a nearby (≈144 Mpc) quiescent galaxy with a low-mass massive black hole (10⁴M_⊙<M_BH< 10⁶M_⊙). AT2022lri belongs to the TDE-H+He subtype. More than 1 Ms of X-ray data were collected with NICER, Swift, and XMM-Newton from 187 to 672 days after peak. The X-ray luminosity gradually declined from 1.5 × 10⁴⁴erg s⁻¹to 1.5 × 10⁴³erg s⁻¹and remains much above the UV and optical luminosity, consistent with a super-Eddington accretion flow viewed face-on. Sporadic strong X-ray dips atop a long-term decline are observed, with a variability timescale of ≈0.5 hr–1 days and amplitude of ≈2–8. When fitted with simple continuum models, the X-ray spectrum is dominated by a thermal disk component with inner temperature going from ∼146 to ∼86 eV. However, there are residual features that peak around 1 keV, which, in some cases, cannot be reproduced by a single broad emission line. We analyzed a subset of time-resolved spectra with two physically motivated models describing a scenario either where ionized absorbers contribute extra absorption and emission lines or where disk reflection plays an important role. Both models provide good and statistically comparable fits, show that the X-ray dips are correlated with drops in the inner disk temperature, and require the existence of subrelativistic (0.1–0.3c) ionized outflows. We propose that the disk temperature fluctuation stems from episodic drops of the mass accretion rate triggered by magnetic instabilities or/and wobbling of the inner accretion disk along the black hole’s spin axis. 

Immersive AR technologies can support students’ learning processes and deep engagement with outdoor science pursuits, yet few studies explore these technologies with out-of-school learners. We analyze how immersive AR features built into an outdoor-based mobile app shaped nine families’ learning experiences as they explored pollinator habitats. Preliminary findings revealed that immersive AR scanning tools built into the Pollinator Explorers app guided families’ observational practices of real-world objects through virtual overlays representing pollinator habitats. 

A series of complexes with low-energy Fe II to Ti IV metal-to-metal charge-transfer (MMCT) transitions, Cp 2 Ti(C 2 Fc) 2 , Cp* 2 Ti(C 2 Fc) 2 , and MeOOC Cp 2 Ti(C 2 Fc) 2 , was investigated using solvatochromism and resonance Raman spectroscopy (RRS) augmented with time-dependent density functional theory (TDDFT) calculations in order to interrogate the nature of the CT transitions. Computational models were benchmarked against the experimental UV-Vis spectra and B3LYP/6-31G(d) was found to most faithfully represent the spectra. The energy of the MMCT transition was measured in 15 different solvents and a multivariate fit to the Catalán solvent parameters – solvent polarizability (SP), solvent dipolarity (SdP), solvent basicity (SB), and solvent acidity (SA) – was performed. The effect of SP indicates a greater degree of electron delocalization in the excited state (ES) than the ground state (GS). The small negative solvatochromism with respect to SdP indicates a smaller dipole moment in the ES than the GS. The effect of SB is consistent with charge-transfer to Ti. Upon excitation into the MMCT absorption band, the RRS data show enhancement of the alkyne stretching modes and of the out-of-plane bending modes of the cyclopentadienyl ring connected to Fe and the alkyne bridge. This is consistent with changes in the oxidation states of Ti and Fe, respectively. The higher-energy transitions (350–450 nm) show enhancement of vibrational modes consistent with ethnylcyclopentadienyl to Ti ligand-to-metal charge transfer (LMCT). The RRS data is consistent with the TDDFT predicted character of these transitions. TDDFT suggests that the lowest-energy transition in Cp 2 Ti(C 2 Fc) 2 CuI, where CuI is coordinated between the alkynes, retains its Fe II to Ti IV MMCT character, in agreement with the RRS data, but that the lowest-energy transitions have significant CuI to Ti character. For Cp 2 Ti(C 2 Fc) 2 CuI, excitation into the low-energy MMCT absorption band results in selective enhancement of the symmetric alkynyl stretching mode.